
Double-layer capacitance is the important characteristic of the which appears at the interface between a and a (for example, between a conductive and an adjacent liquid ). At this boundary two layers of with opposing polarity form, one at the surface of the electrode, and one in the electrolyte. These two layers, on the electrode and ions in the electrolyte, are typically separated by a single layer of [pdf]
The amount of charge stored in double-layer capacitor depends on the applied voltage. The double-layer capacitance is the physical principle behind the electrostatic double-layer type of supercapacitors.
Electric double layer capacitor (EDLC) [1, 2] is the electric energy storage system based on charge–discharge process (electrosorption) in an electric double layer on porous electrodes, which are used as memory back-up devices because of their high cycle efficiencies and their long life-cycles. A schematic illustration of EDLC is shown in Fig. 1.
Binoy K. Saikia, in Journal of Energy Storage, 2022 The capacitance mechanism of Electric Double Layer Capacitors is similar to that of dielectric capacitors. In conventional capacitors, energy is stored by the accumulation of charges on two parallel metal electrodes which separated by dielectric medium with a potential difference between them.
Because an electrochemical capacitor is composed out of two electrodes, electric charge in the Helmholtz layer at one electrode is mirrored (with opposite polarity) in the second Helmholtz layer at the second electrode. Therefore, the total capacitance value of a double-layer capacitor is the result of two capacitors connected in series.
As a part of this renewed interest in electric double-layer capacitors (EDLCs), researchers began seeking new strategies to synthesize high surface area porous carbon-based materials as electrodes for EDLCs to obtain high specific capacitance and high energy density.
Self-discharge is a persistent issue in electric double-layer capacitors (EDLCs), also known as supercapacitors, leading to a decline in cell voltage and the loss of stored energy. Surprisingly, this problem has often been overlooked in the realm of supercapacitor research.

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